Prof. A. Karoui

 

        

   

 

Nanoscience and Nanotechnology Research Center,

Shaw University, Raleigh, NC

 

  

 

Amongst who dream of clean and accessible energy

 

 

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ACADEMIC BACKGROUND

My background is physics and materials science reinforced by  computer simulations and applied mathematics. The major orientation of my R&D work has been on semiconductor for photovoltaics and microelectronics, with emphasis on microscopic and nanoscale electrical and optical characterization in connection with structural analysis of defects and nano-features. I spent more than a decade working on various applied photovoltaic projects, and another decade on characterization, modeling  and processing of ultra high purity semiconductor materials for microelectronics and photovoltaic materials.

 

Research HISTORY

 

I started my research with fabrication and characterization of II-VI solar cells,  then I focused on silicon material properties and photovoltaic devices. This occurred at IMEC,1 during my PhD preparation. Then I cooperated with Helios Technology,2 Pragma,3 and more recently, while at  NCSU,4 with NREL,5 BP Solar,6 and Astropower7 on photovoltaics and many other microelectronics and silicon companies. The major research themes that I have worked on are:

 

1- Semiconductor device modeling and computer simulation (Nonlinear modeling of current-voltage characteristic of solar cells, Impedance Characteristics of solar cells, Quantum Efficiency, Light Beam Induced Current,  material optical parameters by ellipsometry, differential contrast imaging, Confocal Microscopy of etched polycrystalline silicon, light scattering modeling by Ray Tracing technique,...

 

2- Modeling and computer simulation of point defect clustering, defect nucleation, continuum modeling of oxygen precipitation in silicon wafers

 

3- Modeling and computer simulation of early stage point defect formation and clustering in silicon during crystal growth, starting from melting point.

 

4- MeV ion implantation and impurity gettering with Micron Technology Inc.8

 

5- Improvement of Aspen Rapid Thermal Processing tool used in advanced microelectronic device fabrication, 300mm technology, in a joint project with Mattson Technology Inc.9 The investigations were based on: (i) x-ray topography (XRT)  and TEM for analyzing process induced slips and dislocations in silicon wafers, and (ii) non invasive microwave Photo-Conductance Decay (mPCD) for charge carrier lifetime mapping, in combination with XRT for detection of ultra low contamination levels. In furtherance of the analysis of these defects, I have used FTIR, and DLTS for impurity assessment and Raman scattering spectroscopy for local strain detection at wafer contact points.

Under the same joint-project I have analyzed (i)  the dynamics of RTP silicides by mapping the sheet resistance and by modeling the temperature distribution and time profiles, and (ii) RTP of ultra shallow junctions using high precision spreading resistance depth profiling.

 

6- Early work on Injection Level Spectroscopy for identification of impurities (at ultra low level) in semiconductors. This technique, which is an extension of mPCD, was intended to map and identify process induced contamination. Contaminant are introduced at ultra low levels (1E10 cm-3) in the ultra high purity silicon wafers.

 

7- Low level nitrogen doping of ultra high purity CZ and FZ silicon. Nitrogen appeared to be extremely useful for nanoscale defect engineering and for controlling mechanical and electrical properties of silicon.  Extensive nanoscale defect characterization based on HRTEM, Z-contrast and EELS. This analysis is supported by multi-scale modeling. Additionnally, Near Field Optical Imaging was conducted.

 

8- Strained  silicon on graded ultra thin SiGe heterostructures for nanoscale electronics. This interesting subject is a hot topic industry,

 

9- Modeling defect nucleation and growth in ultra high purity silicon, and

 

10- High Performance Computing for materials atomic engineering.

 

Current Research Activity

 

     The objective of my program is to fabricate and/or modify nano-materials and create novel design suitable for nano-device fabrication, particularly solar cells. The main thrust is towards the development of new concepts for photovoltaic devices that do not necessarily rely on conventional photon-hole pair conversion mechanism. This research utilizes multi-scale and multi-phenomena modeling of materials and uses features and nanoscale properties of materials.

      Materials of interest for my research are: silicon for nanotechnology, ultra-thin SiGe films, and carbon materials (including diamond and nanotubes intended for Photovoltaic applications). Suitable analytical techniques that I use are Synchrotron x-ray Probe, Synchrotron High Resolution FTIR, Spectroscopic Ellipsometry, Raman Scattering, Photoluminescence Spectroscopy, Near Field Optical Probe, and HRTEM coupled with Z-contrast and EELS  for measuring  nanoscale properties and modification of nanoscale features. Another research area of interest is Nano-optoelectronic materials and devices such as CNT based sensors, bio-physics of pertinent materials, nanoscale optical methods to analyze local conformal changes of molecules.

TEACHING

         Past and present taught courses include: general physics, microwaves, optoelectronic, photovoltaic materials and devices, and defects in semiconductors. Presently, my teaching program is being reoriented toward nanoscience, nanotechnology, and photovoltaics..

 

 

 

 

 

HRTEM images of precipitates located at  the surface of N doped silicon and their FFT

 

 

 

"Crystal Macro Molecule" of silicon with a substitutional nitrogen pair VN2 used in calculation of nitrogen IR absorption lines.

   
 Energy Bands of a 16,16 CNT

1: Inter unversity Micro-Electronic Center, Katholeik University of Leuven, Belgium

2: Helios Technology, Padova, Italy

3: Pragma S.p.A., Nettuno, Italy

4: North Carolina State University, Raleigh, NC.

5: NREL:     National Renewable Energy Lab., Golden, CO

6: BP Solar, Frederick, Maryland, USA

7: Astropower, Delaware

8: Micron Technology Inc., Boise, ID

9: Mattson Technology Inc., Fremont, CA

 

Comments

 

                                                                        

   

             Room 309, Robert Science Building

             Shaw University,

             118 East SouthSt.,   Raleigh,  N.C. 27601,  U.S.A.

             Phone: 919-719 1998,  274 9411

 

Interested in cooperation? Contact me

 

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